Nickel-containing Alloys For Caustic Soda

Nickel-containing alloys many are used in Caustic Soda

Type: Plate, Pipe

Grade: Nickel 200/201, Monel 400, Monel K500, Inconel 600/601/625, Incoloy 800/825, Hastelloy C22/C276/B2

430, 444, XM-33, XM-27, 304/304L, 316/316L, Alloy 20, Alloy 28, S31254, 2304 (S32304), 2205 (S32205),

2507(S32750), 7-Mo Plus(S32950), C70600, C71500.

Plate Standard: ASTM B162, ASTM B127, ASTM B168, ASTM B424, ASTM B443, ASTM B575, ASTM B625, ASTM B333, ASTM A240, ASTM B171

Pipe Standard: ASTM B161, ASTM B165, ASTM B167, ASTM B163, ASTM B444, ASTM B622, ASTM A268, ASTM A312, ASTM B407, ASTM B729, ASTM B668, ASTM B466, ASTM A790

Plate Dimension: W 1000 – 4000mm x L 1000 – 12000mm x T 3 – 80mm

Pipe Size: NPS 1/2″ – 48 x SCH 5S – XXS

Table 1 Nominal composition of nickel-containing alloys many are used in Caustic Soda
composition, % ASTM Spec.b
Alloy UNS

Number a

 

Ni

 

C

 

Cr

 

Mo

 

Cu

 

Fe

Plate Pipe
Group I – Commercially pure (C.P.) nickel and nickel-copper alloys
200 N02200 99.5 0.08 – – – 0.2 B162 B161
201 N02201 99.5 0.01 – – – 0.2 B162 B161
400 N04400 66.5 0.2 – – Bal 1.2 B127 B165
K500 N05500 66.5 0.25 – – Bal 1.2 B127 B165
Group II – Chromium-containing nickel alloys
600 N06600 76 0.08 15.5 – – 8 B168 B167
601 N06601 60 0.05 23 – – Bal B168 B167
825 N08825 42 0.03 21.5 3 2.25 30 B424 B163
625 N06625 61 0.05 21.5 9 – 2.5 B443 B444
C-22/622 N06022 56 0.01 21.5 13.5 – 4 B575 B622
C-276 N10276 58 0.01 15.5 16 – 5.5 B575 B622
33 R20033 32 0.08 33 1.6 3 32 B625 B622
59 N06059 60 0.01 23 15.5 – 0.7 B575 B622
Group III – Nickel-molybdenum alloys
B-2 N10665 69 0.01 1 28 – 2 B333 B622
Ni-Resist (castings)
Type 1 F41000 15 2 2 – – Bal – –
Type 2 F41002 20 2 2 – – Bal – –
Type D2 F43000 20 2 2 – – Bal – –
Ferritic stainless steels
430 S43000 – 0.05 17 – – Bal A240 A268
444 S44400 – 0.02 18 2 – Bal A240 A268
XM-33 S44626 – 0.03 26 1 – Bal A240 A268
XM-27 S44627 – 0.005 26 1 – Bal A240 A268
29-4 S44700 – 0.005 29 4.0 – Bal A240 A268
Austenitic stainless steels
304 S30400 8 0.04 18 – – Bal A240 A312
304L S30403 8 0.02 18 – – Bal A240 A312
316 S31600 10 0.04 16.5 2.1 – Bal A240 A312
316L S31603 10 0.02 16.5 2.1 – Bal A240 A312
800 N08800 33 0.07 21 – – Bal A240 B407
20 N08020 33 0.02 19.5 2.2 3.2 Bal A240 B729
28 N08028 32 0.03 27 3.5 1 Bal B709 B668
6%Moc S31254 18 0.01 20 6.2 0.7 Bal A240 A312
6%Moc N08367 24 0.01 21 6.2 – Bal A240 A312
Table 1 Nominal composition of nickel-containing alloys many are used in Caustic Soda
Composition, % ASTM Spec.b
 

Alloy

UNS

Number a

 

Ni

 

C

 

Cr

 

Mo

 

Cu

 

Fe

 

Plate

Seamless tube and pipe
Duplex stainless steel
2304 S32304 4 0.02 23 0.3 – Bal A240 A790
2205 S32205 5 0.02 22 3.2 – Bal A240 A790
2507 S32750 7 0.02 25 4 – Bal A240 A790
7-Mo Plus S32950 4 0.03 27.5 2 – Bal A240 A790
S32906 7 0.02 29 2.3 – Bal A240 A790
Copper-nickel alloys
90-10 C70600 10 – – – Bal 1.2 B171 B466
70-30 C71500 31 – – – Bal 0.8 B171 B466

a – UNS numbers beginning with an “N” indicate a nickel alloy, but the definition of a nickel alloy is different than that used by ASTM.

b – in ASTM specifications, most nickel alloys fall into the “B” specifications. However, due to a redefinition of a nickel alloy, a few alloys such as Alloy 20 are being reclassified as stainless steels, and will be included in the “A” specifications. That work is still in progress.

c – the 6% Mo alloys are a series of stainless steels, many of which are proprietary, all with roughly 6%Mo content and roughly equivalent in performance.

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