Nickel-containing Alloys For Caustic Soda

Nickel-containing alloys many are used in Caustic Soda

Type: Plate, Pipe

Grade: Nickel 200/201, Monel 400, Monel K500, Inconel 600/601/625, Incoloy 800/825, Hastelloy C22/C276/B2

430, 444, XM-33, XM-27, 304/304L, 316/316L, Alloy 20, Alloy 28, S31254, 2304 (S32304), 2205 (S32205),

2507(S32750), 7-Mo Plus(S32950), C70600, C71500.

Plate Standard: ASTM B162, ASTM B127, ASTM B168, ASTM B424, ASTM B443, ASTM B575, ASTM B625, ASTM B333, ASTM A240, ASTM B171

Pipe Standard: ASTM B161, ASTM B165, ASTM B167, ASTM B163, ASTM B444, ASTM B622, ASTM A268, ASTM A312, ASTM B407, ASTM B729, ASTM B668, ASTM B466, ASTM A790

Plate Dimension: W 1000 – 4000mm x L 1000 – 12000mm x T 3 – 80mm

Pipe Size: NPS 1/2″ – 48 x SCH 5S – XXS

Table 1 Nominal composition of nickel-containing alloys many are used in Caustic Soda
composition, % ASTM Spec.b
Alloy UNS

Number a

 

Ni

 

C

 

Cr

 

Mo

 

Cu

 

Fe

Plate Pipe
Group I – Commercially pure (C.P.) nickel and nickel-copper alloys
200 N02200 99.5 0.08 0.2 B162 B161
201 N02201 99.5 0.01 0.2 B162 B161
400 N04400 66.5 0.2 Bal 1.2 B127 B165
K500 N05500 66.5 0.25 Bal 1.2 B127 B165
Group II – Chromium-containing nickel alloys
600 N06600 76 0.08 15.5 8 B168 B167
601 N06601 60 0.05 23 Bal B168 B167
825 N08825 42 0.03 21.5 3 2.25 30 B424 B163
625 N06625 61 0.05 21.5 9 2.5 B443 B444
C-22/622 N06022 56 0.01 21.5 13.5 4 B575 B622
C-276 N10276 58 0.01 15.5 16 5.5 B575 B622
33 R20033 32 0.08 33 1.6 3 32 B625 B622
59 N06059 60 0.01 23 15.5 0.7 B575 B622
Group III – Nickel-molybdenum alloys
B-2 N10665 69 0.01 1 28 2 B333 B622
Ni-Resist (castings)
Type 1 F41000 15 2 2 Bal
Type 2 F41002 20 2 2 Bal
Type D2 F43000 20 2 2 Bal
Ferritic stainless steels
430 S43000 0.05 17 Bal A240 A268
444 S44400 0.02 18 2 Bal A240 A268
XM-33 S44626 0.03 26 1 Bal A240 A268
XM-27 S44627 0.005 26 1 Bal A240 A268
29-4 S44700 0.005 29 4.0 Bal A240 A268
Austenitic stainless steels
304 S30400 8 0.04 18 Bal A240 A312
304L S30403 8 0.02 18 Bal A240 A312
316 S31600 10 0.04 16.5 2.1 Bal A240 A312
316L S31603 10 0.02 16.5 2.1 Bal A240 A312
800 N08800 33 0.07 21 Bal A240 B407
20 N08020 33 0.02 19.5 2.2 3.2 Bal A240 B729
28 N08028 32 0.03 27 3.5 1 Bal B709 B668
6%Moc S31254 18 0.01 20 6.2 0.7 Bal A240 A312
6%Moc N08367 24 0.01 21 6.2 Bal A240 A312
Table 1 Nominal composition of nickel-containing alloys many are used in Caustic Soda
Composition, % ASTM Spec.b
 

Alloy

UNS

Number a

 

Ni

 

C

 

Cr

 

Mo

 

Cu

 

Fe

 

Plate

Seamless tube and pipe
Duplex stainless steel
2304 S32304 4 0.02 23 0.3 Bal A240 A790
2205 S32205 5 0.02 22 3.2 Bal A240 A790
2507 S32750 7 0.02 25 4 Bal A240 A790
7-Mo Plus S32950 4 0.03 27.5 2 Bal A240 A790
S32906 7 0.02 29 2.3 Bal A240 A790
Copper-nickel alloys
90-10 C70600 10 Bal 1.2 B171 B466
70-30 C71500 31 Bal 0.8 B171 B466

a – UNS numbers beginning with an “N” indicate a nickel alloy, but the definition of a nickel alloy is different than that used by ASTM.

b – in ASTM specifications, most nickel alloys fall into the “B” specifications. However, due to a redefinition of a nickel alloy, a few alloys such as Alloy 20 are being reclassified as stainless steels, and will be included in the “A” specifications. That work is still in progress.

c – the 6% Mo alloys are a series of stainless steels, many of which are proprietary, all with roughly 6%Mo content and roughly equivalent in performance.

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